Transparent Poly(methyl methacrylate)/ZnO Nanocomposites Based on KH570 Surface Modified ZnO Quantum Dots

被引:17
作者
Wang, Weiying [1 ]
Liu, Jie [1 ]
Yu, Xibin [1 ]
Yang, Guangqian [1 ]
机构
[1] Shanghai Normal Univ, Dept Chem, Shanghai 200234, Peoples R China
关键词
Zinc Oxide; PMMA; KH570; Surface Modification; Nanocomposites; WATER; NANOPARTICLES; NANOCRYSTALS; EMISSION; GROWTH; FILMS; PMMA;
D O I
10.1166/jnn.2010.2223
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Transparent luminescent ZnO embedded PMMA polymer has been synthesized by means of grafting poly(methyl methacrylate) (PMMA) onto the surface of ZnO QDs after g-methacryloxypropyl trimethoxy silane (KH570) modification. The resulting ZnO/PMMA nanocomposites with KH570-modified nanoparticles have better dispersibility and preserve the superior luminescence of ZnO nanoparticles in the nanocomposites. The obtained PMMA/ZnO nanocomposite films show high transparency, high UV-shielding efficiency and improved thermal stability. The obtained nanocomposite was characterized by Fourier transform infrared spectroscopy (FT-IA), transmission electron microscope (TEM), X-ray powder diffraction (XRD), thermogravimetry (TG), ultraviolet-visible (UV-vis) absorption spectroscopy.
引用
收藏
页码:5196 / 5201
页数:6
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