Synthesis of hexylated triethylenetetramine: New ligand for homogeneous atom transfer radical polymerization

被引：33

作者：

Acar, MH ^{[1
]}

Bicak, N ^{[1
]}

机构：

[1] Istanbul Tech Univ, Dept Chem, TR-80626 Istanbul, Turkey

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2003年 / 41卷 / 11期

关键词：

living radical polymerization; metal-organic catalysts organometallic catalysts; atorri transfer radical polymerization (ATRP); ligand; homogeneous polymerization;

D O I：

10.1002/pola.10716

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of hexylated triethylenetetramine (HHTETA), a ligand for homogenous atom transfer radical polymerization (ATRP), was discussed. It was found that when HHTETA was dissolved in S, CuBr and CuBr2 was extracted from aqueous solutions almost quantitatively. The use of HHTETA as a ligand for copper-mediated ATRP in suspension or emulsion polymerization processes was also elaborated.

引用

页码：1677 / 1680

页数：4

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