Synthesis of hexylated triethylenetetramine: New ligand for homogeneous atom transfer radical polymerization

被引：33

作者：

Acar, MH ^{[1
]}

Bicak, N ^{[1
]}

机构：

[1] Istanbul Tech Univ, Dept Chem, TR-80626 Istanbul, Turkey

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2003年 / 41卷 / 11期

关键词：

living radical polymerization; metal-organic catalysts organometallic catalysts; atorri transfer radical polymerization (ATRP); ligand; homogeneous polymerization;

D O I：

10.1002/pola.10716

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of hexylated triethylenetetramine (HHTETA), a ligand for homogenous atom transfer radical polymerization (ATRP), was discussed. It was found that when HHTETA was dissolved in S, CuBr and CuBr2 was extracted from aqueous solutions almost quantitatively. The use of HHTETA as a ligand for copper-mediated ATRP in suspension or emulsion polymerization processes was also elaborated.

引用

页码：1677 / 1680

页数：4

共 43 条

[21]

MATYJASZEWSKI K, 2000, ACS SYM SER, V768, P347

[22] Polymers with very low polydispersities from atom transfer radical polymerization [J].

Patten, TE ;

Xia, JH ;

Abernathy, T ;

Matyjaszewski, K .

SCIENCE, 1996, 272 (5263) :866-868

[23] Copper(I)-catalyzed atom transfer radical polymerization [J].

Patten, TE ;

Matyjaszewski, K .

ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (10) :895-903

[24] LIVING RADICAL POLYMERIZATION OF STYRENE INITIATED BY ARENESULFONYL CHLORIDES AND CU-I(BPY)(N)CL [J].

PERCEC, V ;

BARBOIU, B .

MACROMOLECULES, 1995, 28 (23) :7970-7972

[25] Metal-catalyzed ''living'' radical polymerization of styrene initiated with arenesulfonyl chlorides. From heterogeneous to homogeneous catalysis [J].

Percec, V ;

Barboiu, B ;

Neumann, A ;

Ronda, JC ;

Zhao, MY .

MACROMOLECULES, 1996, 29 (10) :3665-3668

[26] Arenesulfonyl halides: A universal class of functional initiators for metal-catalyzed "living" radical polymerization of styrene(s), methacrylates, and acrylates [J].

Percec, V ;

Barboiu, B ;

Kim, HJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (02) :305-316

[27]

Qiu J, 2000, MACROMOL CHEM PHYSIC, V201, P1625, DOI 10.1002/1521-3935(20000901)201:14<1625::AID-MACP1625>3.0.CO

[28]

2-9

[29] Continuous atom transfer radical block copolymerization of methacrylates [J].

Shen, YQ ;

Zhu, SP .

AICHE JOURNAL, 2002, 48 (11) :2609-2619

[30] Soluble and recoverable support for copper bromide-mediated living radical polymerizatian [J].

Shen, YQ ;

Zhu, SP ;

Pelton, R .

MACROMOLECULES, 2001, 34 (10) :3182-3185

← 1 2 3 4 5 →