Large displacement of germanium atoms in crystalline Ge2Sb2Te5 -: art. no. 081904

被引:49
作者
Shamoto, S [1 ]
Yamada, N
Matsunaga, T
Proffen, T
Richardson, JW
Chung, JH
Egami, T
机构
[1] Japan Atom Energy Res Inst, Neutron Sci Res Ctr, Tokai, Ibaraki 3191195, Japan
[2] Matsushita Elect Ind Co Ltd, Storage Media Syst Dev Ctr, Moriguchi, Osaka 5708501, Japan
[3] Matsushita Technores Inc, Characterizat Technol Grp, Moriguchi, Osaka 5708501, Japan
[4] Los Alamos Natl Lab, Los Alamos, NM 87545 USA
基金
美国国家科学基金会;
关键词
D O I
10.1063/1.1861976
中图分类号
O59 [应用物理学];
学科分类号
摘要
Local structure of NaCl-type crystalline Ge2Sb2Te5 has been studied by the atomic pair distribution function analysis of pulsed neutron powder diffraction data. We have found the large displacement of germanium atoms in this crystalline phase. Usually,, such a large lattice distortion has disadvantages for the electric conductivity. The electronic band structure, however, implies that this significant distortion in addition to the lattice defect at Na site reduces only thermal conductivity, while the highly ordered tellurium atoms at Cl site keep high electric conductivity. (c) 2005 American Institute of Physics.
引用
收藏
页码:1 / 3
页数:3
相关论文
共 17 条
[1]  
Egami T, 2003, PERGAMON MATER SER, V7, pVII
[2]   FREE-CARRIER ABSORPTION IN THE GE-SB-TE SYSTEM [J].
GONZALEZHERNANDEZ, J ;
LOPEZCRUZ, E ;
YANEZLIMON, M ;
STRAND, D ;
CHAO, BB ;
OVSHINSKY, SR .
SOLID STATE COMMUNICATIONS, 1995, 95 (09) :593-596
[3]   Local structure of amorphous GeTe and PdGeSbTe alloy for phase change optical recording [J].
Hirota, K ;
Nagino, K ;
Ohbayashi, G .
JOURNAL OF APPLIED PHYSICS, 1997, 82 (01) :65-70
[4]   X-ray study of the nGeTe•mBi2Te3 mixed layered tetradymite-like compounds [J].
Karpinsky, OG ;
Shelimova, LE ;
Kretova, MA ;
Fleurial, JP .
JOURNAL OF ALLOYS AND COMPOUNDS, 1998, 265 (1-2) :170-175
[5]   Understanding the phase-change mechanism of rewritable optical media [J].
Kolobov, AV ;
Fons, P ;
Frenkel, AI ;
Ankudinov, AL ;
Tominaga, J ;
Uruga, T .
NATURE MATERIALS, 2004, 3 (10) :703-708
[6]   GE K-EDGE EXTENDED X-RAY ABSORPTION FINE-STRUCTURE STUDY OF THE LOCAL-STRUCTURE OF AMORPHOUS GETE AND THE CRYSTALLIZATION [J].
MAEDA, Y ;
WAKAGI, M .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1991, 30 (01) :101-106
[7]   Drude-like behavior of Ge:Sb:Te alloys in the infrared [J].
Mendoza-Galván, A ;
González-Hernández, J .
JOURNAL OF APPLIED PHYSICS, 2000, 87 (02) :760-765
[8]   Electronic and optical properties of SnTe and GeTe [J].
Okoye, CMI .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2002, 14 (36) :8625-8637
[9]   PDFgetN:: a user-friendly program to extract the total scattering structure factor and the pair distribution function from neutron powder diffraction data [J].
Peterson, PF ;
Gutmann, M ;
Proffen, T ;
Billinge, SJL .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2000, 33 :1192-1192
[10]   Building a high resolution total scattering powder diffractometer upgrade of NPD at MLNSC [J].
Proffen, T ;
Egami, T ;
Billinge, SJL ;
Cheetham, AK ;
Louca, D ;
Parise, JB .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2002, 74 (Suppl 1) :S163-S165