Crystalline structures of Sb4 molecules in antimony thin films

被引：27

作者：

Bernhardt, TM

Stegemann, B

Kaiser, B

Rademann, K

机构：

[1] Humboldt Univ, Inst Chem, D-12489 Berlin, Germany

[2] Free Univ Berlin, Inst Expt Phys, D-14195 Berlin, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 02期

关键词：

antimony; scanning probe microscopy; structure elucidation; surface analysis; thin films;

D O I：

10.1002/anie.200390077

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sb4: The building block of a new solidstate modification of antimony. This is a somewhat provocative description of the fact that nanocrystalline structures of Sb4 tetrahedrons exist on the substrates AuSb2(100) and MoS2(0001). Scanning tunneling microscopy images (see picture a and b respectively, each 39 × 39 Å2) of thin amorphous antimony films show such local well-ordered areas with nearly cubic symmetry.

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页码：199 / +

页数：5

相关论文

共 24 条

[1] Unimolecular decomposition of antimony and bismuth cluster ions studied by surface collision induced dissociation mass spectrometry [J].

Bernhardt, TM ;

Kaiser, B ;

Rademann, K .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2002, 4 (07) :1192-1200

[2]

BERNHARDT TM, 1997, THESIS HUMBOLDT U BE

[3] AN EASILY OPERABLE SCANNING TUNNELING MICROSCOPE [J].

BESOCKE, K .

SURFACE SCIENCE, 1987, 181 (1-2) :145-153

[4] SEMICONDUCTING FILMS OF ANTIMONY [J].

COHEN, J .

JOURNAL OF APPLIED PHYSICS, 1954, 25 (06) :798-801

[5] GOLD GROWN EPITAXIALLY ON MICA - CONDITIONS FOR LARGE AREA FLAT FACES [J].

DEROSE, JA ;

THUNDAT, T ;

NAGAHARA, LA ;

LINDSAY, SM .

SURFACE SCIENCE, 1991, 256 (1-2) :102-108

[6]

Donohue J., 1974, STRUCTURES ELEMENTS

[7] Some aspects of the solid state physics of yellow arsenic [J].

Eiduss, J ;

Kalendarev, R ;

Rodionov, A ;

Sazonov, A ;

Chikvaidze, G .

PHYSICA STATUS SOLIDI B-BASIC RESEARCH, 1996, 193 (01) :3-23

[8] CLUSTER-BEAM DEPOSITION OF THIN METALLIC ANTIMONY FILMS - CLUSTER-SIZE AND DEPOSITION-RATE EFFECTS [J].

FUCHS, G ;

MELINON, P ;

AIRES, FS ;

TREILLEUX, M ;

CABAUD, B ;

HOAREAU, A .

PHYSICAL REVIEW B, 1991, 44 (08) :3926-3933

[9] NUCLEATION AND GROWTH OF CRYSTALLITES IN AMORPHOUS ANTIMONY LAYERS ON AS-DEPOSITED ULTRATHIN SUBLAYERS OF METAL - COPPER, SILVER, GOLD, TIN AND LEAD [J].

HASHIMOTO, M ;

UMEZAWA, K ;

MURAYAMA, R .

THIN SOLID FILMS, 1990, 188 (01) :95-108

[10] STUDY OF THE CRYSTALLIZATION OF ANTIMONY THIN-FILMS BY TRANSMISSION ELECTRON-MICROSCOPY OBSERVATIONS AND ELECTRICAL MEASUREMENTS [J].

HOAREAU, A ;

HU, JX ;

JENSEN, P ;

MELINON, P ;

TREILLEUX, M ;

CABAUD, B .

THIN SOLID FILMS, 1992, 209 (02) :161-164