Intramolecular metathesis versus Kharasch reactions using the Grubbs metathesis catalyst: towards catalyst economy

被引：35

作者：

Faulkner, J

Edlin, CD

Fengas, D

Preece, I

Quayle, P ^{[1
]}

Richards, SN

机构：

[1] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England

[2] Avecia, Manchester M9 8ZS, Lancs, England

[3] GlaxoSmithKline, Med Res Ctr, Stevenage SG1 2NY, Herts, England

来源：

TETRAHEDRON LETTERS | 2005年 / 46卷 / 14期

基金：

英国工程与自然科学研究理事会;

关键词：

Grubbs; metathesis; Kharasch; cyclisation; competition; decomposition; stability; ATRC; RCM;

D O I：

10.1016/j.tetlet.2005.02.060

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first generation Grubbs catalyst can promote either ring closing metathesis (RCM) or atom transfer radical cyclisation reactions (ATRC) depending upon the reaction conditions employed. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：2381 / 2385

页数：5

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