Mono(sulfido)-bridged mixed-valence nitrosyl complex: protonation and oxidative addition of iodine across the Ir(II)-Ir(0) bond

被引：16

作者：

Hattori, T

Matsukawa, S

Kuwata, S ^{[1
]}

Ishii, Y

Hidai, M

机构：

[1] Tokyo Inst Technol, Grad Sch Sci & Engn, Dept Appl Chem, Meguro Ku, Tokyo 1528552, Japan

[2] Univ Tokyo, Grad Sch Engn, Dept Chem & Biotechnol, Bunkyo Ku, Tokyo 1138656, Japan

[3] Chuo Univ, Fac Sci & Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1128551, Japan

[4] Sci Univ Tokyo, Fac Ind Sci & Technol, Dept Mat Sci & Technol, Chiba 2788510, Japan

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 04期

关键词：

D O I：

10.1039/b211021k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of [Cp*IrH(SH)(PMe3)] (CP* = eta(5)-C5Me5) with [IrCl2(NO)(PPh3)(2)] in the presence of triethylamine yielded the sulfido-bridged (IrIro)-Ir-II complex [Cp*Ir(PMe3)(mu-S)Ir(NO)(PPh3)], which further reacted with I-2 and triflic acid to give the diiodo complex [Cp*Ir(PMe3)(mu-I)(mu-S)IrI(NO)(PPh3)] and the hydrido complex [Cp*Ir(PMe3)(mu-H)(mu-S)Ir(NO)(PPh3)][OSO2CF3], respectively.

引用

收藏

页码：510 / 511

页数：2

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