Nanostructured materials for advanced automotive de-pollution catalysts

被引:229
作者
Kaspar, J [1 ]
Fornasiero, P [1 ]
机构
[1] Univ Trieste, Dipartimento Sci Chim, I-34127 Trieste, Italy
关键词
three-way catalysts; CeO2-ZrO2 solid solutions; CeO2-ZrO2 mixed oxides; oxygen storage capacity; nanostructured materials; CeO2-ZrO2-Al2O3; nanocomposites;
D O I
10.1016/S0022-4596(02)00141-X
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The present paper reviews the current understanding of CeO2-ZrO2 mixed oxides as promoters of the three-way catalysts. Emphasis is given on the role of the synthesis and it is shown that by adopting an appropriate design of the CeO2-ZrO2 system, nanostructured materials of high thermal stability can be prepared that are suitable for next generation automotive converters. (C) 2002 Elsevier Science (USA). All rights reserved.
引用
收藏
页码:19 / 29
页数:11
相关论文
共 131 条
  • [51] Low-temperature direct synthesis of nanoparticles of fluorite-type ceria-zirconia solid solutions by "forced cohydrolysis at 100°C
    Hirano, M
    Miwa, T
    Inagaki, M
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2001, 158 (01) : 112 - 117
  • [52] Synthesis of CeO2-ZrO2 solid solutions by hydrolysis
    Hirano, M
    Miwa, T
    Inagaki, M
    [J]. JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 2001, 109 (05) : 401 - 405
  • [53] Hydrothermal synthesis and sintering of fine powders in CeO2-ZrO2 system
    Hirano, M
    Kato, E
    [J]. JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 1996, 104 (10) : 958 - 962
  • [54] FORMATION AND CHARACTERIZATION OF CE3ZRO8 PREPARED BY THE HYDRAZINE METHOD
    HIRANO, S
    KAWABATA, A
    YOSHINAKA, M
    HIROTA, K
    YAMAGUCHI, O
    [J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1995, 78 (05) : 1414 - 1416
  • [55] Thermal stability of oxygen storage properties in a mixed CeO2-ZrO2 system
    Hori, CE
    Permana, H
    Ng, KYS
    Brenner, A
    More, K
    Rahmoeller, KM
    Belton, D
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 1998, 16 (02) : 105 - 117
  • [56] Studies of the oxygen release reaction in the platinum-ceria-zirconia system
    Hori, CE
    Brenner, A
    Ng, KYS
    Rahmoeller, KM
    Belton, D
    [J]. CATALYSIS TODAY, 1999, 50 (02) : 299 - 308
  • [57] Improvement of thermal stability of alumina by addition of zirconia
    Horiuchi, T
    Teshima, Y
    Osaki, T
    Sugiyama, T
    Suzuki, K
    Mori, T
    [J]. CATALYSIS LETTERS, 1999, 62 (2-4) : 107 - 111
  • [58] Glycothermal synthesis of zirconia-rare earth oxide solid solutions
    Inoue, M
    Sato, K
    Nakamura, T
    Inui, T
    [J]. CATALYSIS LETTERS, 2000, 65 (1-3) : 79 - 83
  • [59] Oxygen release behaviour of Ce(1-x)ZrxO2 powders and appearance of Ce(8-4y)Zr4yO(14-δ) solid solution in the ZrO2-CeO2-CeO1.5 system
    Izu, N
    Omata, T
    Otsuka-Yao-Matsuo, S
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 1998, 270 (1-2) : 107 - 114
  • [60] Thermal stability of Ce1-xZrxO2 solid solution powders
    Janvier, C
    Pijolat, M
    Valdivieso, F
    Soustelle, M
    Zing, C
    [J]. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 1998, 18 (09) : 1331 - 1337