First radical addition onto ketenimines: a novel synthesis of indoles

被引：43

作者：

Alajarin, M ^{[1
]}

Vidal, A ^{[1
]}

Ortin, MM ^{[1
]}

机构：

[1] Univ Murcia, Fac Quim, Dept Quim Organ, E-30071 Murcia, Spain

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 15期

关键词：

cyclization; indoles; ketenimines; radical reactions;

D O I：

10.1016/S0040-4039(03)00562-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel radical-mediated synthesis of 2-alkyl indoles is described. The method is a nonchain process based on the intramolecular addition of benzylic radicals onto the central carbon atom of a ketenimine function, resulting in a 5-exo-dig cyclization. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

收藏

页码：3027 / 3030

页数：4

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