Polyketide library synthesis: Conformational control in extended polypropionates.

被引：20

作者：

Paterson, I

Scott, JP

机构：

[1] University Chemical Laboratory, Cambridge CB2 1EW, Lensfield Road

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 42期

关键词：

D O I：

10.1016/S0040-4039(97)01752-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The stereoregular heptapropionates 1 and 2 display contrasting conformational properties. The mutually reinforcing conformational determinants in hexol 1 lead to the population of essentially a single extended conformer with a helical twist. (C) 1997 Elsevier Science Ltd.

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收藏

页码：7445 / 7448

页数：4

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