Indium-mediated, highly efficient and diastereoselective addition of cyclic secondary allylic bromides to carbonyl compounds

被引：27

作者：

Khan, FA ^{[1
]}

Prabhudas, B ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India

来源：

TETRAHEDRON | 2000年 / 56卷 / 38期

关键词：

indium; diastereoselectivity; homoallyl alcohol;

D O I：

10.1016/S0040-4020(00)00672-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Indium-mediated addition of 3-bromocyclohexene and 3-bromocyclooctene to a variety of aromatic aldehydes and cyclohexanone proceeds smoothly with excellent syn diastereoselectivity to produce the corresponding cycloalkenyl substituted homoallylic alcohols in good to high yields. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：7595 / 7599

页数：5

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