High rate growth of microcrystalline silicon by VHF-GD at high pressure

被引:96
作者
Graf, U [1 ]
Meier, J [1 ]
Kroll, U [1 ]
Bailat, J [1 ]
Droz, C [1 ]
Vallat-Sauvain, E [1 ]
Shah, A [1 ]
机构
[1] Univ Neuchatel, Inst Microtech, CH-2000 Neuchatel, Switzerland
关键词
thin-film microcrystalline silicon layers; high rate deposition; VHF-GD;
D O I
10.1016/S0040-6090(02)01178-1
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Microcrystalline silicon growth using very high frequency-glow discharge PECVD has been studied under conditions of high pressure and high VHF-power conditions. Hereby, the influence of the total gas flow and the silane concentration on the deposition rate has been investigated. Deposition rates of over 25 Angstrom/s have been achieved at relatively low total gas flows of 100 seem. These high-rate films show device-grade quality with respect to subband gap absorption and microcrystalline structure. Dark conductivity measurements reveal midgap character and transmission electron microscopy investigations confirm a highly crystalline microstructure from the bottom to the top of the muc-Si:H films. These high-rate muc-Si:H layers are very interesting candidates for solar cell and other devices. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:37 / 40
页数:4
相关论文
共 10 条
[1]  
BENEDICT J, 1992, MATER RES SOC SYMP P, V254, P121, DOI 10.1557/PROC-254-121
[2]  
DUBAIL J, 2000, P MAT RES SOC S, V609
[3]  
Fay S., 2000, P 16 EUR PHOT SOL EN, P361
[4]   High rate growth of microcrystalline silicon using a high-pressure depletion method with VHF plasma [J].
Fukawa, M ;
Suzuki, S ;
Guo, LH ;
Kondo, M ;
Matsuda, A .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2001, 66 (1-4) :217-223
[5]   High rate deposition of microcrystalline silicon using conventional plasma-enhanced chemical vapor deposition [J].
Guo, LH ;
Kondo, M ;
Fukawa, M ;
Saitoh, K ;
Matsuda, A .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS, 1998, 37 (10A) :L1116-L1118
[6]   High rate growth of microcrystalline silicon at low temperatures [J].
Kondo, M ;
Fukawa, M ;
Guo, LH ;
Matsuda, A .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2000, 266 :84-89
[7]   ORIGINS OF ATMOSPHERIC CONTAMINATION IN AMORPHOUS-SILICON PREPARED BY VERY HIGH-FREQUENCY (70 MHZ) GLOW-DISCHARGE [J].
KROLL, U ;
MEIER, J ;
KEPPNER, H ;
SHAH, A ;
LITTLEWOOD, SD ;
KELLY, IE ;
GIANNOULES, P .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1995, 13 (06) :2742-2746
[8]  
LAMBERTZ A, 2001, 17 EUR PHOT SOL EN C
[9]   Towards high-efficiency thin-film silicon solar cells with the ''micromorph'' concept [J].
Meier, J ;
Dubail, S ;
Platz, R ;
Torres, P ;
Kroll, U ;
Selvan, JAA ;
Vaucher, NP ;
Hof, C ;
Fischer, D ;
Keppner, H ;
Fluckiger, R ;
Shah, A ;
Shklover, V ;
Ufert, KD .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 1997, 49 (1-4) :35-44
[10]  
SUZUKI S, 2001, TECH DIGEST PVSEC 12, P559