Ionothermal synthesis of two chiral three-dimensional metal-organic frameworks based on D-camphoric acid

被引：4

作者：

Li, L. ^{[1
]}

Chen, S. ^{[1
]}

Ning, Y. J. ^{[1
]}

Bai, Y. ^{[1
]}

Dang, D. B. ^{[1
]}

机构：

[1] Henan Univ, Inst Mol & Crystal Engn, Coll Chem & Chem Engn, Henan Key Lab Polyoxometalate Chem, Kaifeng 475004, Peoples R China

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2014年 / 40卷 / 12期

关键词：

SLOW MAGNETIZATION RELAXATION; BROMIDE IONIC LIQUIDS; COORDINATION POLYMERS; LUMINESCENT PROPERTIES; CRYSTAL-STRUCTURES; 3D MOF; MAGNETISM; SOLVENTS; LIGAND;

D O I：

10.1134/S1070328414120082

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two three-dimensional chiral metal-organic frameworks [PMIm][Co-2(D-Cam)(2)(CH3COO)] (I) and [BMIm][Mn-2(D-Cam)(2)(CH3COO)] center dot H2O (II) (PMIm = 1-propyl-3-methylimidazolium, BMIm = 1-butyl-3-methylimidazolium, D-Cam = D-camphoric acid) have been synthesized under the ionothermal conditions and structurally characterized by IR spectroscopy, elemental analysis, XRPD, and X-ray single-crystal structure analysis (CIF files CCDC nos. 979650 (I) and 979649 (II)). Two structures exhibit similar three-dimentional frameworks constructed by the coordination interactions of binuclear metal secondary building units and two bridging ligands of D-Cam and CH3COO-, in which [PMIm](+) cations for I and [BMIm](+) cations for II as templates are filled in the void of frameworks.

引用

页码：904 / 910

页数：7

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