Mononuclear zinc(II), homodinuclear zinc(II) and heterodinuclear zinc(II)-copper(II) complexes derived from tris[(2-pyridyl)methyl]amine

被引：52

作者：

Adams, H ^{[1
]}

Bailey, NA ^{[1
]}

Fenton, DE ^{[1
]}

He, QY ^{[1
]}

机构：

[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF7,S YORKSHIRE,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1997年 / 09期

关键词：

D O I：

10.1039/a608406k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mononuclear zinc(II), homodinuclear zinc(II) and heterodinuclear zinc(II)-copper(II) complexes derived from tris[(2-pyridyl)methyl]amine (L) have been prepared and characterised. The crystal structures of two mononuclear complexes, [ZnL(Cl)][BPh4]. MeCN and [ZnL(O2CPh)][BPh4] show that the co-ordination geometries around the zinc lose to trigonal bipyramidal and that of the heterodinuclear complex [ZnCuL2(p-O2NC6H4OPO3]-[BPh4](2) . H2O are 5.86 Angstrom and bridged by a phosphate monoester.

引用

页码：1533 / 1539

页数：7

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