Role of network connectivity on the elastic, plastic and thermal behavior of covalent glasses

被引:19
作者
Feng, XW [1 ]
Bresser, WJ [1 ]
Zhang, M [1 ]
Goodman, B [1 ]
Boolchand, P [1 ]
机构
[1] Univ Cincinnati, Dept Elect & Comp Engn & Comp Sci, Cincinnati, OH 45221 USA
关键词
D O I
10.1016/S0022-3093(97)90106-X
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Experiments on chalcogenide glasses show that local elasticity as measured by Raman scattering and the kinetic heat-flow near T-g as established from temperature modulated differential scanning calorimetry each display a threshold behavior associated with network connectivity as defined by the mean coordination, [r], near [r] = [r](c) similar or equal to 2.40. Network plasticity of amorphous group IV networks as deduced from nanometer-indentation hardness measurements varies linearly with [r] once [r] > 2.40. Consequences of these results connecting physical behavior of covalent networks with their connectivity are discussed. (C) 1997 Elsevier Science B.V.
引用
收藏
页码:137 / 143
页数:7
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