Can 4,4′-bipyridine N,N′-dioxide play the same important role as 4,4′-bipyridine in the construction of metal coordination networks and crystal engineering?

被引:77
作者
Long, DL [1 ]
Blake, AJ [1 ]
Champness, NR [1 ]
Schröder, M [1 ]
机构
[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England
关键词
D O I
10.1039/b006679f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Various binding modes of 4,4'-bipyridine N,N'-dioxide (L) for crystal engineering are demonstrated in the complexes [Zn(MeOH)(2)L-3](SiF6). 3MeOH and [ZnL6](NO3)(2), which include examples of M-L coordination bonds, hydrogen-bonding and pi-pi stacking interactions.
引用
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页码:2273 / 2274
页数:2
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