Use of niobium(III) and niobium(V) compounds in catalytic imine metathesis under mild conditions

被引：37

作者：

Bruno, JW ^{[1
]}

Li, XJ ^{[1
]}

机构：

[1] Wesleyan Univ, Dept Chem, Middletown, CT 06459 USA

来源：

ORGANOMETALLICS | 2000年 / 19卷 / 23期

关键词：

D O I：

10.1021/om000613k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The niobium reagents NbCl3(DME) (1) and mer-(DME)Cl3Nb=NPh (6) serve as effective catalysts or precatalysts in imine metathesis reactions with a variety of aldimines. These reactions are particularly convenient because they proceed at room temperature in a period of hours; noteworthy is the fact that I functions as a precatalyst even though it does not contain an imide ligand.

引用

页码：4672 / 4674

页数：3

共 36 条

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