A homologous series of redox-active, dinuclear cations with the bridging ligand 2-(2-pyridyl)-1,8-naphthyridine

被引：37

作者：

Campos-Fernández, CS ^{[1
]}

Xiang, OY ^{[1
]}

Dunbar, KR ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

来源：

INORGANIC CHEMISTRY | 2000年 / 39卷 / 12期

关键词：

D O I：

10.1021/ic991406j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of [M-2(O2CCH3)(2)(CH3CN)(6)] [BF4](2) (M = Mo, Rh) and Ru-2(O2CCH3)(4)Cl with pynp (2-(2-pyridyl)-1,8-naphthyridine) yield the homologous series of cations [M-2(O2CCH3)(2)(pynp)(2)](2+), which were fully characterized by X-ray crystallography, cyclic voltammetry, and UV-visible spectroscopy. Electrochemistry revealed interesting redox chemistry for both the dimolybdenum and diruthenium derivatives, which display class II and class III Robin-Day behavior, respectively, for the four one-electron reversible reductions of the two pynp ligands. [GRAPHICS]

引用

页码：2432 / +

页数：3

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