[Bmim]PF6 and BF4 ionic liquids as novel and recyclable reaction media for aromatic amination

被引：67

作者：

Yadav, JS ^{[1
]}

Reddy, BVS ^{[1
]}

Basak, AK ^{[1
]}

Narsaiah, AV ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Div Organ Chem, Hyderabad 500007, Andhra Pradesh, India

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 10期

关键词：

ionic liquids (ILs); nucleophilic substitution; arylamines;

D O I：

10.1016/S0040-4039(03)00037-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Activated aryl halides undergo smooth nucleophilic substitution reactions with secondary amines in 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim]PF6) or 1-butyl-3-methylimidazolium tetrarluoroborate ([bmim]BF4) ionic liquids (ILs) at room temperature to afford the corresponding arylamines in excellent yields under mild and neutral conditions. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：2217 / 2220

页数：4

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