Synthesis and luminescence properties of lanthanide complexes incorporating a hydralazine-derived chromophore

被引：18

作者：

Burton-Pye, BP ^{[1
]}

Heath, SL ^{[1
]}

Faulkner, S ^{[1
]}

机构：

[1] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England

来源：

DALTON TRANSACTIONS | 2005年 / 01期

关键词：

D O I：

10.1039/b413005g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of 1-hydrazinophthalazine with chloroacetyl chloride yields 3-chloromethyl-1,2,4-triazolo-phthalazine. Reaction of this product with the tris tert-butyl ester of DO3A yields a triazolophthalazine appended macrocycle. Hydrolysis and complexation with lanthanide ions gives access to a series of lanthanide complexes (Ln = Nd, Eu, Yb, Er); these are all luminescent and exhibit sensitisation of the lanthanide centre by the chromophore.

引用

页码：146 / 149

页数：4

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