Synthesis and luminescence properties of lanthanide complexes incorporating a hydralazine-derived chromophore

被引:18
作者
Burton-Pye, BP [1 ]
Heath, SL [1 ]
Faulkner, S [1 ]
机构
[1] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England
关键词
D O I
10.1039/b413005g
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Reaction of 1-hydrazinophthalazine with chloroacetyl chloride yields 3-chloromethyl-1,2,4-triazolo-phthalazine. Reaction of this product with the tris tert-butyl ester of DO3A yields a triazolophthalazine appended macrocycle. Hydrolysis and complexation with lanthanide ions gives access to a series of lanthanide complexes (Ln = Nd, Eu, Yb, Er); these are all luminescent and exhibit sensitisation of the lanthanide centre by the chromophore.
引用
收藏
页码:146 / 149
页数:4
相关论文
共 23 条
[11]   Pyrene-sensitised near-IR luminescence from ytterbium and neodymium complexes [J].
Faulkner, S ;
Carrié, MC ;
Pope, SJA ;
Squire, J ;
Beeby, A ;
Sammes, PG .
DALTON TRANSACTIONS, 2004, (09) :1405-1409
[12]   Lanthanide-sensitized lanthanide luminescence: Terbium-sensitized ytterbium luminescence in a trinuclear complex [J].
Faulkner, S ;
Pope, SJA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (35) :10526-10527
[13]   Time-resolved near-IR luminescence from ytterbium and neodymium complexes of the Lehn cryptand [J].
Faulkner, S ;
Beeby, A ;
Carrié, MC ;
Dadabhoy, A ;
Kenwright, AM ;
Sammes, PG .
INORGANIC CHEMISTRY COMMUNICATIONS, 2001, 4 (04) :187-190
[14]  
FAULKNER S, 2004, COMPREHENSIVE COORDI, V9
[15]  
Hasegawa Y, 2000, ANGEW CHEM INT EDIT, V39, P357, DOI 10.1002/(SICI)1521-3773(20000117)39:2<357::AID-ANIE357>3.0.CO
[16]  
2-M
[17]   Photosensitized near infrared luminescence of ytterbium(III) in proteins and complexes occurs via an internal redox process [J].
Horrocks, WD ;
Bolender, JP ;
Smith, WD ;
Supkowski, RM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (25) :5972-5973
[18]   A systematic study of the photophysical processes in polydentate triphenylene-functionalized Eu3+, Tb3+, Nd3+, Yb3+, and Er3+ complexes [J].
Klink, SI ;
Grave, L ;
Reinhoudt, DN ;
van Veggel, FCJM ;
Werts, MHV ;
Geurts, FAJ ;
Hofstraat, JW .
JOURNAL OF PHYSICAL CHEMISTRY A, 2000, 104 (23) :5457-5468
[19]   Being excited by lanthanide coordination complexes: Aqua species, chirality, excited-state chemistry, and exchange dynamics [J].
Parker, D ;
Dickins, RS ;
Puschmann, H ;
Crossland, C ;
Howard, JAK .
CHEMICAL REVIEWS, 2002, 102 (06) :1977-2010
[20]   Sensitized near-infrared emission from complexes of YbIII, NdIII and ErIII by energy-transfer from covalently attached PtII-based antenna units [J].
Shavaleev, NM ;
Moorcraft, LP ;
Pope, SJA ;
Bell, ZR ;
Faulkner, S ;
Ward, MD .
CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (21) :5283-5291