A phenolysis route to a new type of octanuclear iron(III) wheel:: [Fe8(OH)4(OPh)8(O2CBut)12]

被引：35

作者：

Cañada-Vilalta, C

Pink, M

Christou, G ^{[1
]}

机构：

[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA

[2] Indiana Univ, Dept Chem, Bloomington, IN 47405 USA

[3] Indiana Univ, Ctr Mol Struct, Bloomington, IN 47405 USA

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 11期

关键词：

D O I：

10.1039/b301792c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Alcoholysis of [Fe6O2(OH)(2)(O2CBut)(10)(hep)(2)] (1) affords ferric wheels of different nuclearities: methanol yields [Fe-10(OMe)(20)(O2CBut)(10)], whereas phenol gives the structurally unprecedented wheel [Fe-8(OH)(4)(OPh)(8)(O2CBut)(12)], and the first to contain phenoxide.

引用

页码：1240 / 1241

页数：2

共 27 条

[1] Ammala P, 2000, ANGEW CHEM INT EDIT, V39, P1688, DOI 10.1002/(SICI)1521-3773(20000502)39:9<1688::AID-ANIE1688>3.0.CO
[2] 2-8
[3] Single-molecule magnet behavior of a tetranuclear iron(III) complex. The origin of slow magnetic relaxation in iron(III) clusters
Barra, AL
Caneschi, A
Cornia, A
de Biani, FF
Gatteschi, D
Sangregorio, C
Sessoli, R
Sorace, L
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (22) : 5302 - 5310
[4] Benelli C, 1996, ANGEW CHEM INT EDIT, V35, P1825
[5] PORPHYRIN SPONGES - CONSERVATION OF HOST STRUCTURE IN OVER 200 PORPHYRIN-BASED LATTICE CLATHRATES
BYRN, MP
CURTIS, CJ
HSIOU, Y
KHAN, SI
SAWIN, PA
TENDICK, SK
TERZIS, A
STROUSE, CE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (21) : 9480 - 9497
[6] Two new hexanuclear iron(III) complexes with S=5 ground states
Cañada-Vilalta, C
Rumberger, E
Brechin, EK
Wernsdorfer, W
Folting, K
Davidson, ER
Hendrickson, DN
Christou, G
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (21): : 4005 - 4010
[7] CANADAVILALTA C, UNPUB
[8] EFFECTS OF PHENOXIDE LIGATION ON IRON SULFUR CLUSTERS - PREPARATION AND PROPERTIES OF [FE4S4(OAR)4]2- IONS AND THE STRUCTURE OF [(C2H5)4N]2[FE4S4(OC6H5)4]
CLELAND, WE
HOLTMAN, DA
SABAT, M
IBERS, JA
DEFOTIS, GC
AVERILL, BA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (19) : 6021 - 6031
[9] Polynuclear chromium(III) carboxylates. 1. Synthesis, structure, and magnetic properties of an octanuclear complex with a ring structure
Eshel, M
Bino, A
Felner, I
Johnston, DC
Luban, M
Miller, LL
[J]. INORGANIC CHEMISTRY, 2000, 39 (07) : 1376 - 1380
[10] Frey M, 1998, ANGEW CHEM INT EDIT, V37, P3246

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