A phenolysis route to a new type of octanuclear iron(III) wheel:: [Fe8(OH)4(OPh)8(O2CBut)12]

被引：35

作者：

Cañada-Vilalta, C

Pink, M

Christou, G ^{[1
]}

机构：

[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA

[2] Indiana Univ, Dept Chem, Bloomington, IN 47405 USA

[3] Indiana Univ, Ctr Mol Struct, Bloomington, IN 47405 USA

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 11期

关键词：

D O I：

10.1039/b301792c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Alcoholysis of [Fe6O2(OH)(2)(O2CBut)(10)(hep)(2)] (1) affords ferric wheels of different nuclearities: methanol yields [Fe-10(OMe)(20)(O2CBut)(10)], whereas phenol gives the structurally unprecedented wheel [Fe-8(OH)(4)(OPh)(8)(O2CBut)(12)], and the first to contain phenoxide.

引用

页码：1240 / 1241

页数：2

共 27 条

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