Palladium-catalyzed hydrophosphorylation of allenes leading to regio- and stereoselective formation of allylphosphonates

被引:89
作者
Zhao, CQ [1 ]
Han, LB [1 ]
Tanaka, M [1 ]
机构
[1] Natl Inst Mat & Chem Res, Tsukuba, Ibaraki 3058565, Japan
关键词
D O I
10.1021/om000513e
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Palladium 1,1'-bis(diphenylphosphino)ferrocene complex catalysts promote the addition of HP(O)(OCMe2CMe2O), to terminal allenes to afford the corresponding 1,2-adducts regio- and stereoselectively in high yields.
引用
收藏
页码:4196 / 4198
页数:3
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