Direct monitoring of formation and dissociation of individual metal complexes by single-molecule fluorescence spectroscopy

被引：52

作者：

Kiel, Alexander

Kovacs, Janos

Mokhir, Andriy

Kraemer, Roland

Herten, Dirk-Peter

机构：

[1] Univ Heidelberg, Inst Phys Chem, D-69120 Heidelberg, Germany

[2] Univ Heidelberg, Inst Anorgan Chem, D-69120 Heidelberg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 18期

关键词：

coordination chemistry; fluorescence; kinetics; single-molecule studies;

D O I：

10.1002/anie.200604965

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

For the observation of the coordination states of individual copper(ll) chelate complexes in thermodynamic equilibrium (see picture; TMR = tetramethylrhodamine), single-molecule fluorescence spectroscopy can be used. Application of time-resolved single-molecule spectroscopy opens new prospects for the investigation of reactions in the coordination sphere of metal complexes. (Figure Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：3363 / 3366

页数：4

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