195Pt NMR -: theory and application

被引:269
作者
Still, Brett M. [1 ]
Kumar, P. G. Anil [1 ]
Aldrich-Wright, Janice R. [1 ]
Price, William S. [1 ]
机构
[1] Univ Western Sydney, Coll Hlth & Sci, Nanoscale Org & Dynam Grp, Penrith, NSW 1797, Australia
关键词
D O I
10.1039/b606190g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This critical review highlights the progress in Pt-195 NMR over the last 25 years. In particular, some of the recent applications of Pt-195 NMR in catalytic and mechanistic studies, intermetallics and drug binding studies are discussed. Pt-195 NMR chemical shifts obtained from both theoretical studies and experiments are presented for Pt(0), Pt(II), Pt(III) and Pt(IV) complexes. Pt-195 coupling with various nuclei (viz. coupling constants) have also been collected in addition to data on Pt-195 relaxation. The latest developments in the theoretical knowledge and experimental advances have made Pt-195 NMR into a rich source of information in many fields.
引用
收藏
页码:665 / 686
页数:22
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