Chiral amino alcohols bound to diimines, diamines and dendrimers as chiral ligands for the enantioselective ethylation of N-diphenylphosphinylimines

被引：62

作者：

Suzuki, T ^{[1
]}

Hirokawa, Y ^{[1
]}

Ohtake, K ^{[1
]}

Shibata, T ^{[1
]}

Soai, K ^{[1
]}

机构：

[1] Sci Univ Tokyo, Fac Sci, Dept Appl Chem, Shinjuku Ku, Tokyo 162, Japan

来源：

TETRAHEDRON-ASYMMETRY | 1997年 / 8卷 / 24期

关键词：

D O I：

10.1016/S0957-4166(97)00553-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Chiral diimines, diamines and dendrimers possessing 2, 4 and 8 ephedrine derivatives are utilized as chiral ligands for the enantioselective addition of diethylzinc to N-diphenylphosphinylimines to afford enantiomerically enriched N-diphenylphosphinylamines in up to 93% e.e. (C) 1997 Elsevier Science Ltd. All rights reserved.

引用

页码：4033 / 4040

页数：8

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