Blue-green and red photoluminescence in CaTiO3:Sm

被引:50
作者
de Figueiredo, Alberthmeiry T.
Longo, Valeria M.
de Lazaro, Sergio
Mastelaro, Valmor R.
De Vicente, Fábio S.
Hernandes, Antônio C.
Li, Máximo Siu
Varela, José A.
Longo, Elson
机构
[1] Univ Fed Sao Carlos, LIEC, Dept Quim & Engn Mat, BR-13565905 Sao Carlos, SP, Brazil
[2] Univ Sao Paulo, Inst Fis Sao Carlos, BR-13560970 Sao Carlos, SP, Brazil
[3] UNESP, Inst Quim, LIEC, BR-14801970 Araraquara, SP, Brazil
关键词
luminescence; order-disorder; optical materials; CT : Sm;
D O I
10.1016/j.jlumin.2006.08.100
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Blue-green and red photoluminescence (PL) emission in structurally disordered CaTiO3:Sm (CT:Sm) powders was observed at room temperature with laser excitation at 350.7 nm. The perovskite-like titanate CT:Sm powders prepared by a soft chemical processing at different temperatures of annealing were structurally characterized by X-ray diffraction (XRD) and X-ray absorption near-edge structure (XANES). The results indicate that the generation of the broad PL band is related to order-disorder degree in the perovskitelike structure. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:403 / 407
页数:5
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