Graphene Anchored with Co3O4 Nanoparticles as Anode of Lithium Ion Batteries with Enhanced Reversible Capacity and Cyclic Performance

被引：2271

作者：

Wu, Zhong-Shuai ^{[1
]}

Ren, Wencai ^{[1
]}

Wen, Lei ^{[1
]}

Gao, Libo ^{[1
]}

Zhao, Jinping ^{[1
]}

Chen, Zongping ^{[1
]}

Zhou, Guangmin ^{[1
]}

Li, Feng ^{[1
]}

Cheng, Hui-Ming ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China

来源：

ACS NANO | 2010年 / 4卷 / 06期

基金：

美国国家科学基金会;

关键词：

graphene; cobalt oxide; nanomaterial; anode; lithium-ion batteries; cyclic performance; NEGATIVE ELECTRODE MATERIAL; HIGH-QUALITY GRAPHENE; SN-C COMPOSITE; FACILE SYNTHESIS; LI STORAGE; CARBON; SHEETS; GAS; NANOSTRUCTURES; NANOMATERIALS;

D O I：

10.1021/nn100740x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report a facile strategy to synthesize the nanocomposite of Co3O4 nanoparticles anchored on conducting graphene as an advanced anode material for high-performance lithium-ion batteries. The Co3O4 nanoparticles obtained are 10-30 nm in size and homogeneously anchor on graphene sheets as spacers to keep the neighboring sheets separated. This Co3O4/graphene nanocomposite displays superior Li-battery performance with large reversible capacity, excellent cyclic performance, and good rate capability, highlighting the importance of the anchoring of nanopartides on graphene sheets for maximum utilization of electrochemically active Co3O4 nanopartides and graphene for energy storage applications in high-performance lithium-ion batteries.

引用

页码：3187 / 3194

页数：8

共 58 条

[1] Will advanced lithium-alloy anodes have a chance in lithium-ion batteries? [J].

Besenhard, JO ;

Yang, J ;

Winter, M .

JOURNAL OF POWER SOURCES, 1997, 68 (01) :87-90

[2] Enhanced reversible lithium storage in a nanosize silicon/graphene composite [J].

Chou, Shu-Lei ;

Wang, Jia-Zhao ;

Choucair, Mohammad ;

Liu, Hua-Kun ;

Stride, John A. ;

Dou, Shi-Xue .

ELECTROCHEMISTRY COMMUNICATIONS, 2010, 12 (02) :303-306

[3] Carbon-Silicon Core-Shell Nanowires as High Capacity Electrode for Lithium Ion Batteries [J].

Cui, Li-Feng ;

Yang, Yuan ;

Hsu, Ching-Mei ;

Cui, Yi .

NANO LETTERS, 2009, 9 (09) :3370-3374

[4] Nanostructured Sn-C composite as an advanced anode material in high-performance lithium-ion batteries [J].

Derrien, Gaelle ;

Hassoun, Jusef ;

Panero, Stefania ;

Scrosati, Bruno .

ADVANCED MATERIALS, 2007, 19 (17) :2336-+

[5] Porous Co3O4 nanotubes derived from Co4(CO)12 clusters on carbon nanotube templates:: A highly efficient material for Li-battery applications [J].

Du, Ning ;

Zhang, Hui ;

Chen, Bindi ;

Wu, Jianbo ;

Ma, Xiangyang ;

Liu, Zhihong ;

Zhang, Yiqiang ;

Yang, Deren ;

Huang, Xiaohua ;

Tu, Jiangping .

ADVANCED MATERIALS, 2007, 19 (24) :4505-+

[6] The rise of graphene [J].

Geim, A. K. ;

Novoselov, K. S. .

NATURE MATERIALS, 2007, 6 (03) :183-191

[7] Graphene: Status and Prospects [J].

Geim, A. K. .

SCIENCE, 2009, 324 (5934) :1530-1534

[8]

Gopalakrishnan J., 1985, Bull. Mater. Sci, V7, P201, DOI DOI 10.1557/JMR.2016.328

[9] Nanostructured materials for electrochemical energy conversion and storage devices [J].

Guo, Yu-Guo ;

Hu, Jin-Song ;

Wan, Li-Jun .

ADVANCED MATERIALS, 2008, 20 (15) :2878-2887

[10] A nanostructured Sn-C composite lithium battery electrode with unique stability and high electrochemical performance [J].

Hassoun, Jusef ;

Derrien, Gaelle ;

Panero, Stefania ;

Scrosati, Bruno .

ADVANCED MATERIALS, 2008, 20 (16) :3169-3175

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