Graphene Anchored with Co3O4 Nanoparticles as Anode of Lithium Ion Batteries with Enhanced Reversible Capacity and Cyclic Performance

被引:2271
作者
Wu, Zhong-Shuai [1 ]
Ren, Wencai [1 ]
Wen, Lei [1 ]
Gao, Libo [1 ]
Zhao, Jinping [1 ]
Chen, Zongping [1 ]
Zhou, Guangmin [1 ]
Li, Feng [1 ]
Cheng, Hui-Ming [1 ]
机构
[1] Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
基金
美国国家科学基金会;
关键词
graphene; cobalt oxide; nanomaterial; anode; lithium-ion batteries; cyclic performance; NEGATIVE ELECTRODE MATERIAL; HIGH-QUALITY GRAPHENE; SN-C COMPOSITE; FACILE SYNTHESIS; LI STORAGE; CARBON; SHEETS; GAS; NANOSTRUCTURES; NANOMATERIALS;
D O I
10.1021/nn100740x
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report a facile strategy to synthesize the nanocomposite of Co3O4 nanoparticles anchored on conducting graphene as an advanced anode material for high-performance lithium-ion batteries. The Co3O4 nanoparticles obtained are 10-30 nm in size and homogeneously anchor on graphene sheets as spacers to keep the neighboring sheets separated. This Co3O4/graphene nanocomposite displays superior Li-battery performance with large reversible capacity, excellent cyclic performance, and good rate capability, highlighting the importance of the anchoring of nanopartides on graphene sheets for maximum utilization of electrochemically active Co3O4 nanopartides and graphene for energy storage applications in high-performance lithium-ion batteries.
引用
收藏
页码:3187 / 3194
页数:8
相关论文
共 58 条
[51]   Multilayered Cobalt Oxide Platelets for Negative Electrode Material of a Lithium-Ion Battery [J].
Yao, Wenli ;
Yang, Jun ;
Wang, Jiulin ;
Nuli, Yanna .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2008, 155 (12) :A903-A908
[52]   Synthesis and electrochemical performance of carbon nanofiber-cobalt oxide composites [J].
Yao, Wenli ;
Yang, Jun ;
Wang, Jiulin ;
Tao, Liang .
ELECTROCHIMICA ACTA, 2008, 53 (24) :7326-7330
[53]   Large reversible Li storage of graphene nanosheet families for use in rechargeable lithium ion batteries [J].
Yoo, EunJoo ;
Kim, Jedeok ;
Hosono, Eiji ;
Zhou, Hao-shen ;
Kudo, Tetsuichi ;
Honma, Itaru .
NANO LETTERS, 2008, 8 (08) :2277-2282
[54]   A tin-based amorphous oxide composite with a porous, spherical, multideck-cage morphology as a highly reversible anode material for lithium-ion batteries [J].
Yu, Yan ;
Chen, Chun-Hua ;
Shi, Yi .
ADVANCED MATERIALS, 2007, 19 (07) :993-+
[55]   Cross-Stacked Carbon Nanotube Sheets Uniformly Loaded with SnO2 Nanoparticles: A Novel Binder-Free and High-Capacity Anode Material for Lithium-Ion Batteries [J].
Zhang, Hao-Xu ;
Feng, Chen ;
Zhai, Yong-Chao ;
Jiang, Kai-Li ;
Li, Qun-Qing ;
Fan, Shou-Shan .
ADVANCED MATERIALS, 2009, 21 (22) :2299-+
[56]   From cobalt nitrate carbonate hydroxide hydrate nanowires to porous Co3O4 nanorods for high performance lithium-ion battery electrodes [J].
Zhang, Hui ;
Wu, Jianbo ;
Zhai, Chuanxin ;
Ma, Xiangyang ;
Du, Ning ;
Tu, Jiangping ;
Yang, Deren .
NANOTECHNOLOGY, 2008, 19 (03)
[57]   Facile synthesis of nanoporous γ-MnO2 structures and their application in rechargeable Li-ion batteries [J].
Zhao, Jianzhi ;
Tao, Zhanliang ;
Liang, Jing ;
Chen, Jun .
CRYSTAL GROWTH & DESIGN, 2008, 8 (08) :2799-2805
[58]   Precursor-controlled formation of novel carbon/metal and carbon/metal oxide nanocomposites [J].
Zhi, Linjie ;
Hu, Yong-Sheng ;
El Hamaoui, Bassem ;
Wang, Xuan ;
Lieberwirth, Ingo ;
Kolb, Ute ;
Maier, Joachim ;
Muellen, Klaus .
ADVANCED MATERIALS, 2008, 20 (09) :1727-+