Synthesis and properties of silicon-bridged bithiophenes and application to EL devices

被引：20

作者：

Kunai, A

Ohshita, J

Iida, T

Kanehara, K

Adachi, A

Okita, K

机构：

[1] Hiroshima Univ, Grad Sch Engn, Dept Appl Chem, Higashihiroshima 7398527, Japan

[2] Tsukuba Res Ctr, Japan Chem Innovat Inst, Tsukuba, Ibaraki 3050047, Japan

来源：

SYNTHETIC METALS | 2003年 / 137卷 / 1-3期

关键词：

silole; bithiophene; silicon bridge; alpha-pi conjugation; molecular orbital; electroluminescence;

D O I：

10.1016/S0379-6779(02)00854-8

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Dithienosiloles (DTSs) wear prepared and their optical and electrochemical properties were examined in view of electron-accepting ability of them, in comparison with the results of theoretical calculations. They were found to have low-laying LUMOs, and an EL device with pyridyl-substituted DTS as the electron-transporter exhibited high efficiency of current-luminance energy conversion.

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页码：1007 / 1008

页数：2

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