Optimizing biomimetic gelators constructed from amino acid building blocks

被引：32

作者：

Coates, Ian A. ^{[1
]}

Hirst, Andrew R. ^{[1
]}

Smith, David K. ^{[1
]}

机构：

[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2007年 / 72卷 / 10期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1021/jo070317i

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] This paper reports the use of a range of amino acids to construct diverse gelators, employing structures in which Boc-protected amino acids are attached to either end of an aliphatic diamine spacer chain. The choice of amino acid determines whether nanoscale self-assembly takes place and controls the properties of the resultant material, while the function of the amino acid (e.g., the optical properties of tryptophan) is translated into the self-assembled nanostructured gel.

引用

页码：3937 / 3940

页数：4

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