Insertion of metallated epoxides into zirconacycles

被引：23

作者：

Kasatkin, AN ^{[1
]}

Whitby, RJ ^{[1
]}

机构：

[1] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 27期

基金：

英国工程与自然科学研究理事会;

关键词：

zirconium; zirconacycles; silicon; nitriles; carbenoids; alkenes;

D O I：

10.1016/S0040-4039(00)00805-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Metallated epoxides (epoxysilanes, epoxynitriles, epoxystyrene) insert efficiently into zirconacycles via a 1,2-metallate rearrangement to form intermediates which eliminate Cp2Zr(R)O- to afford substituted alkenes. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：5275 / 5280

页数：6

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