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Electron transport with mobility above 10-3 cm2/Vs in amorphous film of co-planar bipyridyl-substituted oxadiazole
被引:25
作者:
Ichikawa, Musubu
Hiramatsu, Nobuyasu
Yokoyama, Norimasa
Miki, Tetsuzo
Narita, Susumu
Koyama, Toshiki
Taniguchi, Yoshio
机构:
[1] Shinshu Univ, Fac Text Sci & Technol, Dept Funct Polymer Sci, Ueda, Nagano 3868567, Japan
[2] Hodogaya Chem Co Ltd, Tsukuba, Ibaraki 3050841, Japan
[3] Shinshu Univ, Fac Text Sci & Technol, Dept Chem Mat, Ueda, Nagano 3868567, Japan
来源:
PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS
|
2007年
/
1卷
/
01期
关键词:
D O I:
10.1002/pssr.200600051
中图分类号:
T [工业技术];
学科分类号:
08 ;
摘要:
We demonstrate that a bipyridyl substituted (Bpy-OXD) shows high electron mobility that reached 10(-3) cm(2)/Vs. We believe that the high mobility results both the hybrid molecular structure of the two accepting units: bipyridyl and oxadiazole, and the planar molecular structure based on its lack of sterically hindered bulky substituent. The computational analysis elucidates that the amorphous nature of Bpy-OXD in thin-film state probably results from the polymorphic effect in isolated state and the volume effect in solid state.
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页码:R37 / R39
页数:3
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