Photochemical Control of Reversible Encapsulation

被引：71

作者：

Dube, Henry ^{[1
,2
]}

Ajami, Dariush ^{[1
,2
]}

Rebek, Julius, Jr. ^{[1
,2
]}

机构：

[1] Scripps Res Inst, Skaggs Inst Chem Biol, La Jolla, CA 92037 USA

[2] Scripps Res Inst, Dept Chem, La Jolla, CA 92037 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 18期

基金：

瑞士国家科学基金会;

关键词：

azobenzenes; encapsulation; host-guest chemistry; photoisomerization; supramolecular chemistry; PHOTORESPONSIVE CROWN-ETHERS; RESONANCE ENERGY-TRANSFER; CYLINDRICAL CAPSULE; MOLECULAR CAPSULE; MULTICOMPONENT; COMPLEXATION; AZOBENZENE; HOST;

D O I：

10.1002/anie.201000876

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Remote control: Molecules can be transferred in a chemical system between capsules and bulk solution by using light and heat. The principle is based on the isomerization of azobenzene, the trans isomer of which is encapsulated, but the cis isomer is not (see picture; C gray and brown, Br mauve; O red, N blue, H white). The photochemical control can also be used to switch between different capsular assemblies. © 2010 Wiley-VCH Verlag GmbH S. Co. KGaA.

引用

页码：3192 / 3195

页数：4

共 29 条

[11] PHOTOREGULATION OF BIOLOGICAL ACTIVITY BY PHOTOCHROMIC REAGENTS .3. PHOTOREGULATION OF BIOELECTRICITY BY ACETYLCHOLINE RECEPTOR INHIBITORS [J].

DEAL, WJ ;

ERLANGER, BF ;

NACHMANS.D .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1969, 64 (04) :1230-&

[12] Deeply inverted electron-hole recombination in a luminescent antibody-stilbene complex [J].

Debler, Erik W. ;

Kaufmann, Gunnar F. ;

Meijler, Michael M. ;

Heine, Andreas ;

Mee, Jenny M. ;

Pljevaljcic, Goran ;

Di Bilio, Angel J. ;

Schultz, Peter G. ;

Millar, David P. ;

Janda, Kim D. ;

Wilson, Ian A. ;

Gray, Harry B. ;

Lerner, Richard A. .

SCIENCE, 2008, 319 (5867) :1232-1235

[13] Container molecules with portals: Reversibly switchable cycloalkane complexation [J].

Gottschalk, Thomas ;

Jaun, Bernhard ;

Diederich, Francois .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (1-2) :260-264

[14] Pairwise selection of guests in a cylindrical molecular capsule of nanometre dimensions [J].

Heinz, T ;

Rudkevich, DM ;

Rebek, J .

NATURE, 1998, 394 (6695) :764-766

[15]

Heinz T, 1999, ANGEW CHEM INT EDIT, V38, P1136, DOI 10.1002/(SICI)1521-3773(19990419)38:8<1136::AID-ANIE1136>3.0.CO

[16]

2-I

[17] Entropically driven binding in a self-assembling molecular capsule [J].

Kang, JM ;

Rebek, J .

NATURE, 1996, 382 (6588) :239-241

[18] Synthetic molecular motors and mechanical machines [J].

Kay, Euan R. ;

Leigh, David A. ;

Zerbetto, Francesco .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (1-2) :72-191

[19]

Körner SK, 2000, CHEM-EUR J, V6, P187, DOI 10.1002/(SICI)1521-3765(20000103)6:1<187::AID-CHEM187>3.0.CO

[20]

2-I

← 1 2 3 →