Microstructural study of carbonized wood after cell wall sectioning

被引:18
作者
Ishimaru, Kengo [1 ]
Hata, Toshimitsu
Bronsveld, Paul
Imamura, Yuji
机构
[1] Daiwa House Ind Co Ltd, Cent Res Lab, Nara 6310801, Japan
[2] Kyoto Univ, Res Inst Sustainable Humanosphere, Uji, Kyoto 6110011, Japan
[3] Univ Groningen, Dept Appl Phys, NL-9700 AB Groningen, Netherlands
关键词
D O I
10.1007/s10853-006-1361-4
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Wooden blocks of Japanese cedar (Cryptomeria japonica) were carbonized at 700 and 1,800 degrees C. The microstructure was analyzed by transmission electron microscopy (TEM) and mu-Raman spectroscopy of the inner planes of wood cell walls. The predominant structure was of a turbostratic nature and no heterogeneity was observed originating from the original cell walls. TEM observations of samples carbonized at 1,800 degrees C showed ordered regions in the surface layer of cell walls. This result was supported by polarized mu-Raman analysis. It may be caused by the deposition of carbon compounds volatilized from the cell walls during pulse current heating.
引用
收藏
页码:2662 / 2668
页数:7
相关论文
共 16 条
[1]   Carbonized wood monoliths - Characterization [J].
Byrne, CE ;
Nagle, DC .
CARBON, 1997, 35 (02) :267-273
[2]   Silicon carbide nanorods and ceramics from wood [J].
Castro, V ;
Fujisawa, M ;
Hata, T ;
Bronsveld, P ;
Vystavel, T ;
De Hosson, J ;
Kikuchi, H ;
Imamura, Y .
EURO CERAMICS VIII, PTS 1-3, 2004, 264-268 :2267-2270
[3]   RAMAN MICROPROBE STUDIES ON CARBON MATERIALS [J].
CUESTA, A ;
DHAMELINCOURT, P ;
LAUREYNS, J ;
MARTINEZALONSO, A ;
TASCON, JMD .
CARBON, 1994, 32 (08) :1523-1532
[4]   SiC/C composites prepared from wood-based carbons by pulse current sintering with SiO2:: Electrical and thermal properties [J].
Fujisawa, M ;
Hata, T ;
Bronsveld, P ;
Castro, V ;
Tanaka, F ;
Kikuchi, H ;
Furuno, T ;
Imamura, Y .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2004, 24 (13) :3575-3580
[5]   Biomorphic cellular silicon carbide ceramics from wood: I. Processing and microstructure [J].
Greil, P ;
Lifka, T ;
Kaindl, A .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 1998, 18 (14) :1961-1973
[6]   Catalytic graphitization of wood-based carbons with alumina by pulse current heating [J].
Hata, T ;
Ishimaru, K ;
Fujisawa, M ;
Bronsveld, P ;
Vystavel, T ;
De Hosson, J ;
Kikuchi, H ;
Nishizawa, T ;
Imamura, Y .
FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES, 2005, 13 :435-445
[7]   Catalytic carbonization of wood charcoal: graphite or diamond? [J].
Hata, T ;
Vystavel, T ;
Bronsveld, P ;
DeHosson, J ;
Kikuchi, H ;
Nishimiya, K ;
Imamura, Y .
CARBON, 2004, 42 (5-6) :961-964
[8]   MICROTEXTURE OF NONGRAPHITIZING CARBONS AND TEM STUDIES OF SOME ACTIVATED SAMPLES [J].
HUTTEPAIN, M ;
OBERLIN, A .
CARBON, 1990, 28 (01) :103-111
[9]   RAMAN-SPECTRA OF GRAPHITE EDGE PLANES [J].
KATAGIRI, G ;
ISHIDA, H ;
ISHITANI, A .
CARBON, 1988, 26 (04) :565-571
[10]   Microstructural evolution during charcoal carbonization by X-ray diffraction analysis [J].
Kercher, AK ;
Nagle, DC .
CARBON, 2003, 41 (01) :15-27