A convenient approach to cyclic enol phosphates via ring-closing metathesis

被引：47

作者：

Whitehead, A ^{[1
]}

Moore, JD ^{[1
]}

Hanson, PR ^{[1
]}

机构：

[1] Univ Kansas, Dept Chem, Lawrence, KS 66045 USA

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 22期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4039(03)00873-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A strategy employing the second generation Grubbs catalyst in order to facilitate the generation of a variety of cyclic enol phosphates, including 2H-chromen-4-yl, 1,2-dihydroquinolin-4-yl, 2H-thiochromen-4-yl, 2H-thiochromen-4-yl 1,1-dioxide, and benzofuran-2-yl enol phosphate scaffolds is described. This work represents the first case of an olefin metathesis reaction in which one of the groups participating in the metathesis event is an enol phosphate moiety. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：4275 / 4277

页数：3

共 37 条

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