Selective Perborate Signaling by Deprotection of Fluorescein and Resorufin Acetates

被引：47

作者：

Choi, Myung Gil ^{[1
]}

Cha, Sunyoung ^{[1
]}

Park, Ji Eun ^{[1
]}

Lee, Haekyung ^{[1
]}

Jeon, Hye Lim ^{[1
]}

Chang, Suk-Kyu ^{[1
]}

机构：

[1] Chung Ang Univ, Dept Chem, Seoul 156756, South Korea

来源：

ORGANIC LETTERS | 2010年 / 12卷 / 07期

关键词：

SODIUM PERBORATE; HYDROGEN-PEROXIDE; LIVING CELLS; ORGANIC-SYNTHESIS; FRESH-WATER; CHEMODOSIMETER; PROBE; PERCARBONATE; TOXICITY; FLUORIDE;

D O I：

10.1021/ol100126c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The acetate derivatives of fluorescein and resorufin exhibited a prominent turn-on type signaling behavior toward BO3- Ions over other common anions. Signaling is based on the selective deprotection of acetate groups by perborate, which resulted in significant chromogenic and fluorogenic signaling. Compound 1 also exhibited a pronounced perborate selectivity over other commonly used oxidants in 90% aqueous acetonitrile solution.

引用

收藏

页码：1468 / 1471

页数：4

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