Dimensional encapsulation of I-•••I2•••I- in an organic salt crystal matrix

被引：91

作者：

Abate, Antonio ^{[1
,2
]}

Brischetto, Manuel ^{[1
,2
]}

Cavallo, Gabriella ^{[1
,2
]}

Lahtinen, Manu ^{[3
]}

Metrangolo, Pierangelo ^{[1
,2
]}

Pilati, Tullio ^{[4
]}

Radice, Stefano ^{[5
]}

Resnati, Giuseppe ^{[1
,2
,4
]}

Rissanen, Kari ^{[6
]}

Terraneo, Giancarlo ^{[1
,2
]}

机构：

[1] Politecn Milan, NFMLab, I-20131 Milan, Italy

[2] Politecn Milan, CNST IIT POLIMI, DCMIC Giulio Natta, I-20131 Milan, Italy

[3] Univ Jyvaskyla, Dept Chem, FI-40014 Jyvaskyla, Finland

[4] Univ Milan, ISTM, CNR, I-20133 Milan, Italy

[5] Solvay Solexis SpA, I-20121 Bollate, MI, Italy

[6] Univ Jyvaskyla, Dept Chem, Nanosci Ctr, FI-40014 Jyvaskyla, Finland

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 16期

关键词：

IODIDE IONIC LIQUID; POLYIODIDE; COMPLEXES; HALOGEN; TEMPLATE; I-4(2-); COBALT;

D O I：

10.1039/b924423a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bis(trimethylammonium) hexane diiodide encapsulates iodine from solution and through a gas/solid reaction yielding in a predictable and controllable manner the selective formation of the rare polyiodide species I-center dot center dot center dot I-I center dot center dot center dot I-, which matches in length to the chosen dication.

引用

页码：2724 / 2726

页数：3

共 38 条

[1] THE GROTTHUSS MECHANISM [J].

AGMON, N .

CHEMICAL PHYSICS LETTERS, 1995, 244 (5-6) :456-462

[2]

BARRANS Y, 1967, CR ACAD SCI C CHIM, V264, P876

[3] Synthesis, characterization, and crystal structures of new dications bearing the -Se-Se- bridge [J].

Bigoli, F ;

Demartin, F ;

Deplano, P ;

Devillanova, FA ;

Isaia, F ;

Lippolis, V ;

Mercuri, ML ;

Pellinghelli, MA ;

Trogu, EF .

INORGANIC CHEMISTRY, 1996, 35 (11) :3194-3201

[4]

Blake AJ, 1998, CHEM SOC REV, V27, P195

[5] VAN DER WAALS VOLUMES + RADII [J].

BONDI, A .

JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) :441-+

[6] Stereochemical studies of cobalt ethylenediamine complexes and their tetrathionate salts: Interactions between complex configuration and tetrathionate conformation [J].

Casadesus, Meritxell ;

Coogan, Michael P. ;

Davies, Elenna ;

Ooi, Li-Ling .

INORGANICA CHIMICA ACTA, 2008, 361 (01) :63-78

[7] Structural and Raman spectroscopic studies as complementary tools in elucidating the nature of the bonding in polyiodides and in donor-I2 adducts [J].

Deplano, P ;

Ferraro, JR ;

Mercuri, ML ;

Trogu, EF .

COORDINATION CHEMISTRY REVIEWS, 1999, 188 :71-95

[8] CRYSTAL-STRUCTURES OF POLYIODIDE SALTS AND MOLECULAR-COMPLEXES .6. CRYSTAL-STRUCTURE OF TETRAKIS(PHENACETIN) DIHYDROGENTETRAIODIDE DIHYDRATE ([H5C2OC6H4N(H)C(CH3)=O]4-H2I4-2H2O) [J].

HERBSTEIN, FH ;

KAPON, M ;

SCHWOTZER, W .

HELVETICA CHIMICA ACTA, 1983, 66 (01) :35-43

[9] THE STRUCTURE OF A SOLUTION-GROWN CRYSTAL OF 1,4-DIIODOBENZENE [J].

HINCHLIFFE, A ;

MUNN, RW ;

PRITCHARD, RG ;

SPICER, CJ .

JOURNAL OF MOLECULAR STRUCTURE, 1985, 130 (1-2) :93-96

[10] PREPARATION OF NEW VANADIUM(II) IODIDES AND CRYSTAL-STRUCTURE OF HEXAKIS(ACETONITRILE)VANADIUM(II) (TETRAIODIDE) [J].

HITCHCOCK, PB ;

HUGHES, DL ;

LEIGH, GJ ;

SANDERS, JR ;

DESOUZA, J ;

MCGARRY, CJ ;

LARKWORTHY, LF .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (24) :3683-3687

← 1 2 3 4 →