One "Click" to controlled bifunctional supported catalysts for the Cu/TEMPO-catalyzed aerobic oxidation of alcohols

被引：37

作者：

Fernandes, Antony E. ^{[1
,2
]}

Riant, Olivier ^{[1
]}

Jonas, Alain M. ^{[1
]}

Jensen, Klavs F. ^{[2
]}

机构：

[1] Catholic Univ Louvain, Inst Condensed Matter & Nanosci, B-1348 Louvain La Neuve, Belgium

[2] MIT, Dept Chem Engn, Cambridge, MA 02139 USA

来源：

RSC ADVANCES | 2016年 / 6卷 / 43期

关键词：

MESOPOROUS SILICA NANOPARTICLES; HETEROGENEOUS SYNERGISTIC CATALYSIS; TSUJI-TROST REACTION; COOPERATIVE CATALYSIS; FUNCTIONAL-GROUPS; SELECTIVE OXIDATION; REUSABLE CATALYSTS; PALLADIUM COMPLEX; TERMINAL ALKYNES; SUZUKI-MIYAURA;

D O I：

10.1039/c6ra05026c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A simple and reliable methodology is described for the preparation of heterogeneous bifunctional catalysts with a high control over surface composition. The strategy relies on the grafting of a mix of catalytic components from an azide-functionalized silica platform using the CuAAC reaction. The resulting finely engineered supported catalysts are employed in the model Cu/TEMPO-catalyzed aerobic oxidation of benzylic alcohol.

引用

页码：36602 / 36605

页数：4

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