Enantioselective addition of diethylzinc to aldehydes catalyzed by optically active 1,4-aminoalcohols

被引：44

作者：

Hanyu, N

Aoki, T

Mino, T

Sakamoto, M

Fujita, T

机构：

[1] Chiba Univ, Fac Engn, Dept Mat Technol, Inage Ku, Chiba 2638522, Japan

[2] Chiba Univ, Grad Sch Sci & Technol, Inage Ku, Chiba 2638522, Japan

来源：

TETRAHEDRON-ASYMMETRY | 2000年 / 11卷 / 14期

关键词：

D O I：

10.1016/S0957-4166(00)00263-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Enantioselective addition reactions of diethylzinc to aldehydes were performed by catalytic reactions with chiral 1,4-aminoalcohols, Optically active 1,4-aminoalcohols were synthesized from (+)-camphor and (-)-fenchone through foul steps involving iodine-mediated lactonization of 3-hydroxy acids. (C) 2000 Elsevier Science Ltd. All rights reserved.

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页码：2971 / 2979

页数：9

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