Palladated Kaiser oxime resin as precatalyst for the Heck reaction in organic and aqueous media

被引：35

作者：

Alacid, Emilio

Najera, Carmen

机构：

[1] Univ Alicante, Fac Ciencias, Dept Quim Organ, Alicante 03080, Spain

[2] Univ Alicante, Inst Sintesis Organ, Alicante 03080, Spain

来源：

SYNLETT | 2006年 / 18期

关键词：

Heck reaction; palladacycles; polymers; alkenes; arylation;

D O I：

10.1055/s-2006-951521

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A particular Kaiser oxime resin derived palladacycle is an efficient precatalyst for the Heck reaction with aryl iodides and bromides in DMF and in aqueous solvents under relatively moderate temperatures (110 degrees C and 120 degrees C) and high TON up to 10(5). Poisoning studies indicate that this polymer acts as a precatalyst. The polymer has been reused after recycling with low to moderate leaching of Pd(0).

引用

收藏

页码：2959 / 2964

页数：6

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