Photophysical poperties of Schiff-base metal complexes

被引：130

作者：

Cozzi, PG ^{[1
]}

Dolci, LS ^{[1
]}

Garelli, A ^{[1
]}

Montalti, M ^{[1
]}

Prodi, L ^{[1
]}

Zaccheroni, N ^{[1
]}

机构：

[1] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy

来源：

NEW JOURNAL OF CHEMISTRY | 2003年 / 27卷 / 04期

关键词：

D O I：

10.1039/b209396k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The photophysical behaviour of Schiff-base complexes with several different metals has been investigated. Among these complexes, the one with aluminium (3) presents interesting features, showing good chemical stability, high absorption coefficients and fluorescence quantum yield. In addition, the fluorescence intensity of 3 udergoes appreciable changes in the presence of coordinating species, such as carboxylate anions, allowing the association process to be monitored with high sensitivity. In addition, we have demonstrated that, if suitable groups are attached to the carboxylate function, supramolecular systems with interesting properties can be designed and characterised.

引用

页码：692 / 697

页数：6

共 48 条

[1] A new class of aluminum cations based upon tetradentate (N2O2) chelating ligands [J].

Atwood, DA ;

Jegier, JA ;

Rutherford, D .

INORGANIC CHEMISTRY, 1996, 35 (01) :63-70

[2] Group 13 compounds incorporating salen ligands [J].

Atwood, DA ;

Harvey, MJ .

CHEMICAL REVIEWS, 2001, 101 (01) :37-52

[3] [Cr(Salen)] as a 'bridge' between asymmetric catalysis, Lewis acids and redox processes [J].

Bandini, M ;

Cozzi, PG ;

Umani-Ronchi, A .

CHEMICAL COMMUNICATIONS, 2002, (09) :919-927

[4] Recent developments in transition metal ion detection by luminescent chemosensors [J].

Bargossi, C ;

Fiorini, MC ;

Montalti, M ;

Prodi, L ;

Zaccheroni, N .

COORDINATION CHEMISTRY REVIEWS, 2000, 208 :17-32

[5]

Binstead R. A., 1996, SPECFIT

[6] An efficient method for controlled propylene oxide polymerization: The significance of bimetallic activation in aluminum Lewis acids [J].

Braune, W ;

Okuda, J .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (01) :64-68

[7] Towards novel biolabels: synthesis of a tagged highly fluorescent Schiff-base aluminium complex [J].

Briggs, MSJ ;

Fossey, JS ;

Richards, CJ ;

Scott, B ;

Whateley, J .

TETRAHEDRON LETTERS, 2002, 43 (29) :5169-5171

[8] Chiral Schiff base complexes of copper(II), vanadium(IV) and nickel(II) as oxidation catalysts.: X-ray crystal structures of [Cu(R-salpn)(OH2)] and [Cu(±-busalcx)] [J].

Bunce, S ;

Cross, RJ ;

Farrugia, LJ ;

Kunchandy, S ;

Meason, LL ;

Muir, KW ;

O'Donnell, M ;

Peacock, RD ;

Stirling, D ;

Teat, SJ .

POLYHEDRON, 1998, 17 (23-24) :4179-4187

[9] Utilisation of homogeneous and supported chiral metal(salen) complexes in asymmetric catalysis [J].

Canali, L ;

Sherrington, DC .

CHEMICAL SOCIETY REVIEWS, 1999, 28 (02) :85-93

[10] Electronic structures of nitridomanganese(V) complexes [J].

Chang, CJ ;

Connick, WB ;

Low, DW ;

Day, MW ;

Gray, HB .

INORGANIC CHEMISTRY, 1998, 37 (12) :3107-3110

← 1 2 3 4 5 →