Cationic terminal borylenes by halide abstraction: Synthesis and spectroscopic and structural characterization of an Fe=B double bond

被引：114

作者：

Coombs, DL ^{[1
]}

Aldridge, S ^{[1
]}

Jones, C ^{[1
]}

Willock, DJ ^{[1
]}

机构：

[1] Cardiff Univ, Dept Chem, Cardiff CF10 3TB, S Glam, Wales

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 21期

关键词：

D O I：

10.1021/ja0346936

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and the spectroscopic and structural characterization of the cationic terminal borylene complex [Cp*Fe(CO)2(BMes)]+ are reported. Halide abstraction from the corresponding bromoboryl species using Na[BArf4] generates the borylene as the [BArf4]- salt in ca. 50% yield. Analyses of IR, NMR, crystallographic, and DFT data are consistent with the presence of an FeB double bond. Copyright © 2003 American Chemical Society.

引用

页码：6356 / 6357

页数：2

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