Enhanced photocurrent generations in RuL2(NCS)2/di-(3-aminopropyl)-viologen self-assembled on In2O3

被引：18

作者：

Lee, Wonjoo

Mane, R. S.

Lee, Soo-Hyoung

Han, Sung-Hwan

机构：

[1] Chonbuk Natl Univ, Div Environm & Chem Engn, Jeonju 561756, South Korea

[2] Hanyang Univ, Dept Chem, Seoul 133791, South Korea

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2007年 / 9卷 / 07期

关键词：

photosensors; In2O3; self-assembled monolayers; photocurrent; chemical bath deposition;

D O I：

10.1016/j.elecom.2007.02.012

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A Ru(2,2'-bipriding-4,4'-dicarboxylic acid(2)(NCS)(2) [RuL2(NCS)(2)]/di-(3-aminoprophyl)-viologen (DAPV)/In2O3 nanorod system was prepared and applied for photocurrent generation with its maximum surface area. The In2O3 nanorods were prepared using the chemical-bath-deposition method. The various surface morphology of /In2O3 were obtained by adding different amounts of 0.1 M HCl solution to the indium-containing solution. The DAPV and RuL2(NCS)(2) were easily self-assembled on the indium-oxide surface. The energy levels of RuL2(NCS)(2), DAPV, In2O3, and tin-doped indium-oxide (ITO) were well arranged, and the systems forms an efficient acceptor-sensitizer. The photocurrent measurement of the systems showed exellent photocurrent of 50 nA/cm(2) under the air mass (AM) 1.5 condition (100 mW/cm(2)), which was increased by a factor of ten compared to ones without indium-oxide layers. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：1502 / 1507

页数：6

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