Very rapid preparation of SmI2 by sonic treatment of iodoform and metallic samarium

被引：56

作者：

Concellón, JM ^{[1
]}

Rodríguez-Solla, H ^{[1
]}

Bardales, E ^{[1
]}

Huerta, M ^{[1
]}

机构：

[1] Univ Oviedo, Dept Quim Organ & Inorgan, E-33071 Oviedo, Spain

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 2003卷 / 09期

关键词：

samarium; sonication; synthetic methods;

D O I：

10.1002/ejoc.200210669

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A very rapid preparation of SmI2 by sonication of a mixture of metallic samarium and iodoform in THF is described. To prove the synthetic applications of the obtained SmI2 several high-yielding reactions were carried out. Preliminary results for the generation of SmI2 in THF by sonication from diiodomethane, 1,2-diiodoethane, or iodine are also described. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).

引用

页码：1775 / 1778

页数：4

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