New materials from high-pressure experiments

被引:504
作者
McMillan, PF
机构
[1] UCL, Dept Chem, Christopher Ingold Labs, London WC1H 0AJ, England
[2] UCL Royal Inst Great Britain, Davy Faraday Res Lab, London W1S 4BS, England
关键词
D O I
10.1038/nmat716
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
High-pressure synthesis on an industrial scale is applied to obtain synthetic diamonds and cubic boron nitride (c-BN), which are the superhard abrasives of choice for cutting and shaping hard metals and ceramics. Recently, high-pressure science has undergone a renaissance, with novel techniques and instrumentation permitting entirely new classes of high-pressure experiments. For example, superconducting behaviour was previously known for only a few elements and compounds. Under high-pressure conditions, the,superconducting periodic table' now extends to all classes of the elements, including condensed rare gases, and ionic compounds such as Csl. Another surprising result is the newly discovered solid-state chemistry of light-element 'gas' molecules such as CO2, N-2 and N2O. These react to give polymerized covalently bonded or ionic mineral structures under conditions of high pressure and temperature: the new solids are potentially recoverable to ambient conditions. Here we examine innovations in high-pressure research that might be harnessed to develop new materials for technological applications.
引用
收藏
页码:19 / 25
页数:7
相关论文
共 95 条
[71]   Shock-induced transformation of β-Si3N4 to a high-pressure cubic-spinel phase [J].
Sekine, T ;
He, HL ;
Kobayashi, T ;
Zhang, M ;
Xu, FF .
APPLIED PHYSICS LETTERS, 2000, 76 (25) :3706-3708
[72]   High-temperature metastability of cubic spinel Si3N4 [J].
Sekine, T ;
Mitsuhashi, T .
APPLIED PHYSICS LETTERS, 2001, 79 (17) :2719-2721
[73]   Cubic Si6-zAlzOzN8-z (z=1.8 and 2.8) spinels formed by shock compression [J].
Sekine, T ;
He, H ;
Kobayashi, T ;
Tansho, M ;
Kimoto, K .
CHEMICAL PHYSICS LETTERS, 2001, 344 (3-4) :395-399
[74]   Superconductivity in the nonmagnetic state of iron under pressure [J].
Shimizu, K ;
Kimura, T ;
Furomoto, S ;
Takeda, K ;
Kontani, K ;
Onuki, Y ;
Amaya, K .
NATURE, 2001, 412 (6844) :316-318
[75]   High pressure-high temperature investigation of the stability of nitride spinels in the systems Si3N4-Ge3N4 [J].
Soignard, E ;
Somayazulu, M ;
Mao, HK ;
Dong, JJ ;
Sankey, OF ;
McMillan, PF .
SOLID STATE COMMUNICATIONS, 2001, 120 (5-6) :237-242
[76]  
SOIGNARD E, UNPUB PHYS REV LETT
[77]   Mechanical properties of cubic BC2N, a new superhard phase [J].
Solozhenko, VL ;
Dub, SN ;
Novikov, NV .
DIAMOND AND RELATED MATERIALS, 2001, 10 (12) :2228-2231
[78]   Novel broken symmetry phase from N2O at high pressures and high temperatures -: art. no. 135504 [J].
Somayazulu, M ;
Madduri, A ;
Goncharov, AF ;
Tschauner, O ;
McMillan, PF ;
Mao, HK ;
Hemley, RJ .
PHYSICAL REVIEW LETTERS, 2001, 87 (13)
[79]  
STANLEY HE, 2001, IN PRESS NATO ADV RE
[80]   Superconductivity at 10-17 K in compressed sulphur [J].
Struzhkin, VV ;
Hemley, RJ ;
Mao, HK ;
Timofeev, YA .
NATURE, 1997, 390 (6658) :382-384