Addition reaction of azido-exTTFs to C60:: Synthesis of fullerotriazoline and azafulleroid electroactive dyads

被引：53

作者：

González, S

Martín, N

Swartz, A

Guldi, DM

机构：

[1] Univ Complutense, Fac Ciencias Quim, Dept Quim Organ, E-28040 Madrid, Spain

[2] Univ Notre Dame, Radiat Lab, Notre Dame, IN 46556 USA

来源：

ORGANIC LETTERS | 2003年 / 5卷 / 04期

关键词：

D O I：

10.1021/ol027473q

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] The addition reaction of azido-exTTFs to C-60 affords electroactive fullerotriazoline and azafulleroid dyads, which behave as amphoteric redox systems. Fluorescence experiments and transient absorption spectroscopy reveal that excitation of the fullerene moiety leads to radical pair lifetimes that are 2 orders of magnitude higher than those previously reported for related fullerotriazolines.

引用

页码：557 / 560

页数：4

共 34 条

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