Synthesis of New Enantiomerically Pure Organoiodine Catalysts and Their Application in the α-Functionalization of Ketones

被引：50

作者：

Farooq, Umar ^{[1
,2
]}

Schaefer, Sascha ^{[1
]}

Shah, Azhar-ul-Haq Ali ^{[1
,3
]}

Freudendahl, Diana Maria ^{[1
]}

Wirth, Thomas ^{[1
]}

机构：

[1] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, S Glam, Wales

[2] COMSATS Inst Informat Technol, Abbottabad, Pakistan

[3] Kohat Univ Sci & Technol, Kohat, Pakistan

来源：

SYNTHESIS-STUTTGART | 2010年 / 06期

关键词：

hypervalent iodine reagents; organocatalysis; oxidation; stereoselective synthesis; HYPERVALENT IODINE COMPOUNDS; M-CHLOROPERBENZOIC ACID; POLYVALENT IODINE; CHEMISTRY; <HYDROXY(TOSYLOXY)IODO>BENZENE; TOSYLOXYLATION; IODOARENES; OXIDATION; ALKENES;

D O I：

10.1055/s-0029-1218640

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of enantiomerically pure iodoarenes and their application to the alpha-oxysulfonylation of propiophenone, and the lactonization of 5-oxo-5-phenylpentanoic acid using MCPBA as stoichiometric oxidant are reported to give useful synthetic intermediates in good yields and moderate enantioselectivities.

引用

页码：1023 / 1029

页数：7

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