Activation of hydrogen- and halogen-bonding interactions in tetrathiafulvalene-based crystalline molecular conductors

被引：516

作者：

Fourmigué, M ^{[1
]}

Batail, P ^{[1
]}

机构：

[1] Univ Angers, UMR 6200 CNRS, UFR Sci, Lab Chim Ingn Mol & Mat CIMMA, F-49045 Angers, France

来源：

CHEMICAL REVIEWS | 2004年 / 104卷 / 11期

关键词：

D O I：

10.1021/cr030645s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An overview is given of the effort accomplished to direct intermolecular interactions in crystalline molecular conductors based on tetrathiafulvalene (TTF) derivatives. Focus is on the use of directional, electrostatic, normal, and weak hydrogen bonds and halogen bonds. Specifically, tetrathiafulvalene molecules functionalized by hydrogen-bonding donor or acceptor groups such as alcohols, carboxylic acids, and amides as well as halogenated tetrathiafulvalenes and their salts, are covered, specifically concentrating on the crystal structures they adopt in the solid state.

引用

页码：5379 / 5418

页数：40

共 194 条

[61] Single crystalline commensurate metallic assemblages of π-slabs and Cdl2-type layers:: Synthesis and properties of β-(EDT-TTF-l2)2[Pb5/6□1/6l2]3 and β-(EDT-TTF-l2)2[Pb2/3+xAg1/3-2x□xl2]3, x=0.05 [J].

Devic, T ;

Evain, M ;

Moëlo, Y ;

Canadell, E ;

Auban-Senzier, P ;

Fourmigué, M ;

Batail, P .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (11) :3295-3301

[62]

Devic T, 2002, EUR J INORG CHEM, P2844

[63] Cation radical salts of cyano(ethylenedithio)tetrathiafulvalene with halogenated anions:: annihilation of the CN•••Hal interaction and stabilisation of conducting, antiferromagnetic square or chain-type salts [J].

Devic, T ;

Bertran, JN ;

Domercq, B ;

Canadell, E ;

Avarvari, N ;

Auban-Senzier, P ;

Fourmigué, M .

NEW JOURNAL OF CHEMISTRY, 2001, 25 (11) :1418-1424

[64] 1,1-bis(3',4,4'-trimethyltetrathiafulvalen-3-yl)ethanol ethanol hemisolvate; A new bifunctional pi-donor molecule [J].

Dolbecq, A ;

Fourmigue, M ;

Batail, P .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1996, 52 :1543-1545

[65] FROM RACEMIC MIXTURES OF CHIRAL PI-DONOR MOLECULES TO MIXED STACKS OF H-BONDED CENTROSYMMETRICAL DIMERS OF CATION AND ANION-RADICALS WITH SINGLET-TRIPLET EXCITATIONS - THE EXAMPLE OF [(+/-)ME3TTF-C-ASTERISK-H(MEOH).+]2[TCNQ.-]2 (TTF = TETRATHIAFULVALENE - TCNQ = TETRACYANOQUINODIMETHANE) [J].

DOLBECQ, A ;

FOURMIGUE, M ;

BATAIL, P ;

COULON, C .

CHEMISTRY OF MATERIALS, 1994, 6 (08) :1413-1418

[66] Relative basicities of the oxygen atoms of the Linquist polyoxometalate [Mo6O19]2- and their recognition by hydroxyl groups in radical cation salts based on functionalized tetrathiafulvalene π donors [J].

Dolbecq, A ;

Guirauden, A ;

Fourmigué, M ;

Boubekeur, K ;

Batail, P ;

Rohmer, MM ;

Bénard, W ;

Coulon, C ;

Sallé, M ;

Blanchard, P .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (08) :1241-1248

[67]

Dolbecq A, 1996, B SOC CHIM FR, V133, P83

[68] Me(3)TTF-PO3H2, a redox phosphonic acid and its monoanilinium salt [PhNH(3)(+)][Me(3)TTF-PO(OHO-], the electrocrystallized neutral (zwitterionic) pi radical [Me(3)TTF-PO(OHO-](.+), and their associated lamellar constructions in the solid state [J].

Dolbecq, A ;

Fourmigue, M ;

Krebs, FC ;

Batail, P ;

Canadell, E ;

Clerac, R ;

Coulon, C .

CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (10) :1275-1282

[69] Hal•••Hal interactions in a series of three isostructural salts of halogenated tetrathiafulvalenes.: Contribution of the halogen atoms to the HOMO-HOMO overlap interactions [J].

Domercq, B ;

Devic, T ;

Fourmigué, M ;

Auban-Senzier, P ;

Canadell, E .

JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (06) :1570-1575

[70]

Dumas J.-M., 1983, Halides, Pseudo-Halidesand Azides, P985

← 2 3 4 5 6 7 8 9 10 11 →